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Optimality of nonconservative driving for finite-time processes with discrete states
Benedikt Remlein1, Udo Seifert1
1II. Institut für Theoretische Physik, Universität Stuttgart, 70550 Stuttgart, Germany.
Abstract:
An optimal finite-time process drives a given initial distribution to a given final one in a given time at the lowest cost as quantified by total entropy production. We prove that for a system with discrete states this optimal process involves nonconservative driving, i.e., a genuine driving affinity, in contrast to the case of a system with continuous states. In a multicyclic network, the optimal driving affinity is bounded by the number of states within each cycle. If the driving affects forward and backwards rates nonsymmetrically, the bound additionally depends on a structural parameter characterizing this asymmetry.
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