Is froth flotation a potential scheme for microplastics removal? Analysis on flotation kinetics and surface...

Increasing microplastics (MPs) cause significant threats to the ecosystem and society. The tremendous advances concerning the sources, occurrence, chemical behavior, toxicology, and ecological effects contribute to the emerging MPs removal. Based on the intrinsic hydrophobicity of MPs, froth flotation can remove MPs from water environments via bubble attachment on hydrophobic surfaces. This study comprehensively investigated plastic, aqueous, and operating variables in the flotation removal of polyethylene terephthalate (PET) and polystyrene (PS) MPs, assisted by numerous bench-scale experiments and a first-order model with rectangular distribution of floatability. Froth flotation performed better to remove MPs with higher density, larger size, and lower concentration. K⁺ (0-50 mM), Na⁺ (0-150 mM), and Ca²⁺ (0-10 mM) did not affect the flotation recovery of MPs. MPs particles could be thoroughly removed by froth flotation when humic acid (HA) and Al³⁺ concentrations were less than 30 mg/L and 0.05 mM, respectively. 100% of MPs could be removed at a rapid flotation rate under aeration volume of 5.4 mL/min and frother dosage of 28 mg/L. Non-covalent interactions and near-surface water film might favor the adhesion of hydrophilic species and obstruct the flotation removal of MPs. The froth flotation-based MPs removal had potential application in multiple flow systems due to its simplicity and continuity.