Electrospun Polyacrylonitrile/Clinoptilolite Coating for SPME of PAHs from Water Samples

Electrospun polyacrylonitrile/clinoptilolite (PAN/CP) nanofibers were used to extract polycyclic aromatic hydrocarbons (PAHs) (acenaphthene, acenaphthylene, naphthalene, and phenanthrene) from water samples by solid-phase microextraction (SPME). The target PAHs was detected and quantified by gas chromatography equipped with a flame ionization detector. The PAN/CP fibrous coating with uniform morphology and without beads was electrospun after optimizing the electrospinning parameters by the Taguchi method. Thermogravimetric analysis of PAN/CP nanofibers indicated that the nanofibers are thermally stable up to 357°C. The effective parameters that affect the extraction by SPME were optimized using the response surface methodology based on the central composite design. The limits of detection and limits of quantification by the proposed method were 0.10-0.32 and 0.45-1.12 ng mL-1, respectively. The relative standard deviations were below 12%. The method was assessed for extracting PAHs from real samples including agricultural water, rainwater and spring water. The obtained relative recoveries were higher than 86%.