Evolution of fusion and PCDD/F-signatures of boiler ash from a mechanical grate municipal solid waste incinerator

Boiler ash formed at different temperature ranges in a typical mechanical grate incinerator is collected and systemically studied, with the aim of providing a reference for ash disposal and revealing the formation routes and distribution of polychlorinated ρ-dibenzodioxins and dibenzofurans (PCDD/Fs). Key physical and chemical properties are carefully analyzed, including chemical component, ash fusion temperatures (AFTs), crystalline phases, chemical species, and PCDD/Fs. Several fouling and slagging indices are introduced and their relationships with AFT are revealed. The fouling index (F_u) and a slagging index (R_b/a×Na) are well fitted with ash flow temperatures, with correlation coefficient (R²) of 0.82 and 0.82, respectively; these could be better potential indices for disposal applications of municipal solid waste incineration fly ash. CC/C-C/C-H (69.25-80.93%) and inorganic chlorine (94.23-98.68%) are the dominant carbon and chlorine species, respectively. The increasing AFT is mainly attributed to the changing components, the increasing proportions of crystalline CaSO₄, NaCl and KCl and the decreasing crystallinity and content of SiO₂. Twice as much PCDD/Fs is generated by the low-temperature heterogeneous reaction (6.71-19.22 ng/g) than by the high-temperature homogeneous reaction (0.59-6.71 ng/g). The proportions of highly chlorinated homologues increase and gradually become the main component. Principal component analysis reveals that PCDD/Fs is positively correlated with Cl, Cu, Pb, Sn, Sb, Zn and CC/C-C/C-H but negatively correlated with less volatile elements, e.g., Ni, Mn, Al, Ti, Si, and Cr. These results can benefit further research on boiler ash disposal and PCDD/F formation routes in the post-combustion area of incinerators.