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Updated: Oct 31, 2025

A Method to Manipulate Surface Tension of a Liquid Metal via Surface Oxidation and Reduction
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Conversion of Polymer Surfaces into Nonwetting Substrates for Liquid Metal Applications.

Sachin Babu1, Behnoush Dousti1, Gil Sik Lee1

  • 1Department of Electrical and Computer Engineering, University of Texas at Dallas, 800 West Campbell Road, Richardson, Texas 75080, United States.

Langmuir : the ACS Journal of Surfaces and Colloids
|June 28, 2021
PubMed
Summary
This summary is machine-generated.

A novel plasma treatment makes common polymers non-wetting for liquid metals. This process enhances surface roughness and fluorination, crucial for advanced liquid metal applications.

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Area of Science:

  • Materials Science
  • Surface Science
  • Polymer Science

Background:

  • Liquid metal applications are hindered by polymer wetting on oxidized gallium-based liquid metals.
  • Developing non-wetting polymer surfaces is critical for advancing liquid metal technologies.

Purpose of the Study:

  • To investigate the effect of CF4/O2 plasma treatment on polymer surfaces for liquid metal applications.
  • To convert wetting polymer surfaces into non-wetting (lyophobic) surfaces for gallium-based liquid metals.

Main Methods:

  • Polymer surfaces (PDMS, SU8, S1813, polyimide) were treated with CF4/O2 plasma for 120 seconds.
  • Contact angle measurements (static, advancing, receding) were used to quantify wetting behavior.
  • X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) analyzed surface chemistry and topography.

Main Results:

  • Plasma treatment resulted in contact angles >150° (static/advancing) and >140° (receding), indicating significant lyophobic behavior.
  • Surface analysis revealed simultaneous fluorination and a substantial increase in surface roughness (sub-micron scale).
  • The Cassie-Baxter state, driven primarily by roughness, was suggested as the mechanism for non-wetting properties.

Conclusions:

  • CF4/O2 plasma treatment effectively transforms wetting polymer surfaces into non-wetting ones for gallium-based liquid metals.
  • Surface roughness, augmented by plasma treatment, is the dominant factor in achieving lyophobic behavior.
  • This method offers a versatile approach to reduce surface free energy and enhance compatibility in liquid metal-polymer systems.