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Updated: Oct 31, 2025

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Ta4BTe8: Tantalum Telluride Cluster Chains with Encapsulated Boron Atoms
Holger Kleinke1, E Wolfgang Finckh1, Wolfgang Tremel1
1Institut für Anorganische Chemie und Analytische Chemie der Universität, Duesbergweg, D-55099 Mainz (Germany), Fax: (+49) 6131-39-3922.
Abstract:
The new metallic chain compound Ta4BTe8 has been synthesized by high-temperature reactions from the elements. The structure consists of chains of fused B-centered Ta6Te12 clusters (shown in the picture), the individual chains being connected by ditelluride groups. The results of band structure calculations indicate that the interstitial B atoms are required for cluster stability.
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