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Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
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In convection, thermal energy is carried by the large-scale flow of matter. Ocean currents and large-scale atmospheric circulation, which result from the buoyancy of warm air and water, transfer hot air from the tropics toward the poles and cold air from the poles toward the tropics. The Earth’s rotation interacts with those flows, causing the observed eastward flow of air in the temperate zones. Convection dominates heat transfer by air, and the amount of available space for the airflow...
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Peripheral thermosensation is the perception of external temperature. A change in temperature (on the surface of the skin and other tissues) is detected by a family of temperature-sensitive ion channels called Transient Receptor Potential, or TRP, receptors. These receptors are located on free nerve endings. Those detecting cold temperatures are closer to the surface of the skin than the nerve endings detecting warmth. These thermoTRP channels, while temperature selective, have relatively...
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Heat transfer between the human body and its environment occurs through four main mechanisms: conduction, convection, radiation, and evaporation.
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Just as interesting as the effects of heat transfer on a system are the methods by which the heat transfer occur. Whenever there is a temperature difference, heat transfer occurs. It may occur rapidly, such as through a cooking pan, or slowly, such as through the walls of a picnic ice box. So many processes involve heat transfer that it is hard to imagine a situation where no heat transfer occurs. Yet, every heat transfer takes place by only three methods: conduction, convection, and radiation.
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Magnetically enhanced thermoelectrics: a comprehensive review.

Fu-Hua Sun1,2, Shifang Ma2, Wenyu Zhao2

  • 1Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Foshan 528225, People's Republic of China.

Reports on Progress in Physics. Physical Society (Great Britain)
|June 30, 2021
PubMed
Summary

Magnetically enhanced thermoelectric materials offer significant potential for waste-energy recycling and cooling. This review explores how magnetism influences thermoelectric properties, paving the way for advanced sustainable energy solutions.

Keywords:
magnetic transitionmagnetoelectric couplingmagnon-dragnonsaturating Seebecksuperparamagnetismthermoelectrics

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Sustainable Energy

Background:

  • Thermoelectric (TE) materials are crucial for waste-energy recycling and solid-state cooling.
  • TE conversion efficiency hinges on thermal and electrical transport properties.
  • Magnetically enhanced thermoelectrics present a promising avenue for sustainable energy and fundamental physics research.

Purpose of the Study:

  • To review state-of-the-art thermoelectric materials from a magnetism perspective.
  • To discuss magnetically induced thermoelectric effects and their underlying mechanisms.
  • To highlight strategies for improving thermoelectric figure of merit (ZT) and identify research challenges.

Main Methods:

  • Analysis of thermoelectric materials considering charge, lattice, orbit, and spin degrees of freedom.
  • Discussion of magnetically induced thermoelectric effects, including electron scattering, magnetoelectric coupling, and magnon/phonon-drag Seebeck effects.
  • Review of thermal-electronic and spin current-induced thermoelectric materials.

Main Results:

  • Magnetism significantly impacts thermoelectric properties through various mechanisms.
  • Superparamagnetism and magnetic transitions enhance electron scattering, boosting efficiency.
  • Field-dependent magnetoelectric coupling and magnon/phonon-drag effects offer further control over thermoelectric performance.

Conclusions:

  • Magnetically enhanced thermoelectrics hold substantial promise for sustainable energy applications.
  • Further research into thermal-electronic and spin current-induced effects is crucial for improving ZT.
  • Addressing ongoing research challenges is vital for advancing this nascent field.