A highly sensitive photoelectrochemical aptasensor based on BiVO₄ nanoparticles-TiO₂ nanotubes for detection of PCB72

In this work, a simple and highly sensitive photoelectrochemical (PEC) aptasensor has been developed for detecting PCB72 based on TiO₂ nanotubes (NTs) decorated with BiVO₄ nanoparticles (NPs). The BiVO₄ NPs-TiO₂ NTs composites prepared through a simple hydrothermal method exhibit good visible-light adsorption ability, high PEC response and perfect photo-excited stability. The synthesized composites were explored as the photoactive sensing materials for development of a PEC sensing platform for the first time. Here, Au nanoparticles (NPs) were first deposited the composites, and the anti-PCB72 aptamer molecules were immobilized on the Au NPs-deposited BiVO₄ NPs-TiO₂ NTs. The developed PEC aptasensor exhibits high sensitivity and specificity for PCB72 with a wide linear range from 1 ng/L to 500 ng/L and a low detection limit of 0.23 ng/L. The application of the aptasensor was evaluated by determining PCB 72 in the environment water samples. Thus, a simple and efficient PEC sensing platform was established for detecting the content of PCBs in the environment.