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![The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10SiSiMe334]2- Using a Metastable SnI Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Ligated aluminum cluster anions, LAl- (n = 1-14, L = N[Si(Me)3]2)
Gaoxiang Liu1, Sandra M Ciborowski1, Georgia R Montone2
1Department of Chemistry, Johns Hopkins University, Baltimore, MD 21218, USA. kbowen@jhu.edu.
Abstract:
A wide range of low oxidation state aluminum-containing cluster anions, LAln- (n = 1-14, L = N[Si(Me)3]2), were produced via reactions between aluminum cluster anions and hexamethyldisilazane (HMDS). These clusters were identified by mass spectrometry, with a few of them (n = 4, 6, and 7) further characterized by a synergy of anion photoelectron spectroscopy and density functional theory (DFT) based calculations. As compared to a previously reported method which reacts anionic aluminum hydrides with ligands, the direct reactions between aluminum cluster anions and ligands promise a more general synthetic scheme for preparing low oxidation state, ligated aluminum clusters over a large size range. Computations revealed structures in which a methyl-group of the ligand migrated onto the surface of the metal cluster, thereby resulting in "two metal-atom" insertion between Si-CH3 bond.
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