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Updated: Oct 29, 2025

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Phenothiazine functional materials for organic optoelectronic applications
Palivela Siva Gangadhar1, Govind Reddy2, Seelam Prasanthkumar1
1Polymers & Functional Materials Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500007, TS, India. giribabu@iict.res.in and Academy of Scientific and Innovation Research (AcSIR), Ghaziabad, 201002, India.
Abstract:
Phenothiazine (PTZ) is one of the most extensively investigated S, N heterocyclic aromatic hydrocarbons due to its unique optical, electronic properties, flexibility of functionalization, low cost, and commercial availability. Hence, PTZ and its derivative materials have been attractive in various optoelectronic applications in the last few years. In this prospective, we have focused on the most significant characteristics of PTZ and highlighted how the structural modifications such as different electron donors or acceptors, length of the π-conjugated system or spacers, polar or non-polar chains, and other functional groups influence the optoelectronic properties. This prospective provides a recent account of the advances in phenothiazine derivative materials as an active layer(s) for optoelectronic (viz. dye sensitized solar cells (DSSCs), perovskite solar cells (PSCs), organic solar cells (OSCs), organic light-emitting diodes (OLEDs), organic field-effect transistor (OFETs), chemosensing, nonlinear optical materials (NLOs), and supramolecular self-assembly applications. Finally, future prospects are discussed based on the structure-property relationship in PTZ-derivative materials. This overview will pave the way for researchers to design and develop new PTZ-functionalized structures and use them for various organic optoelectronic applications.
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