Periodic Polarization Waves in a Strained, Highly Polar Ultrathin SrTiO₃

SrTiO₃ is generally paraelectric with centrosymmetric structure exhibiting unique quantum fluctuation related ferroelectricity. Here we reveal highly polar and periodic polarization waves in SrTiO₃ at room temperature, which is stabilized by periodic tensile strains in a sandwiched PbTiO₃/SrTiO₃/PbTiO₃ structure. Scanning transmission electron microscopy reveals that periodic a/c domain structures in PbTiO₃ layers exert unique periodic tensile strains in the ultrathin SrTiO₃ layer and consequently make the highly polar and periodic states of SrTiO₃. The as-received polar SrTiO₃ layer features peak polar ion displacement of ∼0.01 nm and peak tetragonality of ∼1.07. These peak values are larger than previous results, which are comparable to that of bulk ferroelectric PbTiO₃. Our results suggest that it is possible to integrate large and periodic strain state in oxide films with exotic properties, which in turn could be useful in optical applications and information addressing when used as memory unit.