Quantitative analysis on the mechanism of Cd²⁺ removal by MgCl₂-modified biochar in aqueous solutions

In this study, a pristine biochar (BC) and MgCl₂-modified biochar (MBC) were prepared using Pennisetum sp. straw for removing Cd²⁺ from aqueous solutions. Scanning electron microscope (SEM) imaging combined with energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), as well as the surface area and porosity analyses were used to reveal the physico-chemical characteristics of the pristine and modified adsorbents. Results suggested that MgCl₂ impregnation during the synthesis had enhanced the specific surface area and pore volume of the biochar. Batch adsorption experiments indicated that the Cd²⁺ adsorption data of MBC fitted the Langmuir isothermal and pseudo-second order kinetic models, indicating a chemical adsorption was undergoing in the system. The maximum adsorption capacity of Cd²⁺ on MBC was 763.12 mg/g, which was 11.15 times higher than that of the pristine BC. The Cd²⁺ removal by MBC was mainly attributed to the mechanisms in an order: Cd(OH)₂ precipitation (73.43%) > ion exchange (22.67%) > Cd²⁺-π interaction (3.88%), with negligible contributions from functional group complexation, electrostatic attraction and physical adsorption. The MBC could thus be used as a promising adsorbent for Cd²⁺ removal from aqueous solutions.