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This study visualizes polymer aging pathways using fluorescent probes. It reveals how humidity and oxygen content influence polyimide degradation, enabling better material lifespan prediction and control.

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Area of Science:

  • Polymer Science
  • Materials Chemistry
  • Analytical Chemistry

Background:

  • Current polymer aging studies lack spatiotemporal resolution, hindering the distinction of multiple degradation pathways.
  • Understanding diverse aging mechanisms is crucial for predicting and controlling polymer evolution under various environmental factors.

Purpose of the Study:

  • To develop a method for visualizing and distinguishing multiple polymer aging pathways simultaneously.
  • To investigate the influence of hydrothermal treatment on polyimide aging mechanisms.

Main Methods:

  • Utilized specific fluorescent probes to label hydroxyl, carboxyl, and amino groups during polyimide aging via boron-oxygen, imine, and thiourea linkages.
  • Employed controlled excitation and emission wavelengths to visualize aging pathways in 3D fluorescent images.
  • Analyzed the impact of humidity and oxygen content on pyrolysis and hydrolysis pathways.

Main Results:

  • Successfully visualized individual and simultaneous multi-paths in polyimide aging using 3D fluorescent imaging.
  • Destructured hydrothermal aging into distinct pyrolysis and hydrolysis pathways.
  • Discovered that increased humidity and decreased oxygen accelerate hydrolysis and hinder pyrolysis, leading to severe polyimide degradation.
  • Quantified that oxygen has a greater regulatory effect on pyrolysis than water vapor on hydrolysis.

Conclusions:

  • Developed a multidimensional identification methodology for polymer aging pathways.
  • Demonstrated that tuning oxygen and water vapor content can guide polymer aging towards less harmful outcomes.
  • Provides insights for enhancing the long-term use and controlled degradation of polymers.