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Evaluation of Integrated Anaerobic Digestion and Hydrothermal Carbonization for Bioenergy Production
Published on: June 15, 2014
Study of the interrelationship between nano-TiO2 addition and photo-fermentative bio-hydrogen production of corn
Tian Zhang1, Danping Jiang1, Yameng Li1
1Key Laboratory of New Materials and Facilities for Rural Renewable Energy (MOA of China), Henan Agricultural University, Zhengzhou 450002, China.
Abstract:
This study explored the interrelationship between nano-TiO2 addition and photo-fermentative hydrogen production (PFHP) of corn straw. The maximum cumulative hydrogen volume (CHV) was up to 688.8 mL under the optimal photo-fermentative process conditions with nano-TiO2 addition of 300 mg/L. Initial pH and interaction between substrate concentration and light intensity had highly significant effects on PFHP of corn straw with nano-TiO2 addition. With the improvement of CHV, nano-TiO2 addition decreased the optimal initial pH and substrate concentration for PFHP of corn straw. Moreover, nano-TiO2 addition promoted the metabolism of butyric acid and acetic acid by photosynthetic bacteria HAU-M1, and significantly reduced the total concentration of intermediate byproducts during hydrogen production to a low level of 1.6-2.5 g/L, thus making the CHV, maximum hydrogen production rate (HPR) and average hydrogen content (HC) increased by 32.6%, 27.9% and 8.3% respectively over the control without nano-TiO2 addition.

