Single-atom nanozymes and environmental catalysis: A perspective

The nanomaterials intrinsic enzyme-like activity has gained enormous traction since its discovery in 2007 by Gao and colleagues. The wide range of applications with nanozymes made it more attractive among the scientific community across the world. The area of artificial-enzymes is still evolving, with the development of Single-Atom Nanozymes (SANs), and there is a lot of opportunity in the design and development of SANs that has plenty of real-time applications. The irregular active site distribution or truncated densities of active sites present on the surface of nanozymes can be result in the reduced activity and specificity of nanozymes. Individually spreading these active sites evenly on a solid support will help to curtail the uneven distribution of active sites, resulting in the formation of SANs. SANs, like homogeneous catalysts, are very effective and active due to the nearly uniform distribution of active sites on solid support, and their recovery and recyclability, like heterogeneous catalysts, make them green and sustainable. This review provides a brief overview of architecture, synthesis, and implementations of SANs in various fields. Also, the possibility of SANs in environmental catalysis is discussed along with the key challenges and prospects lying ahead in this field.