An integrated biological-electrocatalytic process for highly-efficient treatment of coking wastewater

Coking wastewater is typically refractory, mainly due to its biological toxicity and complex composition. In this study, a novel integrated biological-electrocatalytic process consisting of two three-dimensional electrochemical reactors (3DERs), two biological aerated filters (BAFs), and a three-dimensional biofilm electrode reactor (3DBER) is developed for the advanced treatment of coking wastewater. 73.21% of chemical oxygen demand (COD), 38.02% of ammonium nitrogen (NH₄⁺-N) and 91.46% of nitrate nitrogen (NO₃^--N) are removed by 3DERs. BAFs mainly convert NH₄⁺-N to NO₃^--N through microbial nitrification. The 3DBER removes the residual NO₃^--N by bio-electrochemical denitrification. The integrated system can eliminate 74.72-83.27% of COD, 99.38-99.74% of NH₄⁺-N, and 69.64-99.83% of total nitrogen from coking wastewater during the continuous operation, as well as significantly reducing the toxicity of the wastewater. The superiorities of the integrated 3DERs/BAFs/3DBER system recommend the application of such biological-electrocatalytic technology in the treatment of highly toxic wastewater.