Zr-doped CoFe-layered double hydroxides for highly efficient seawater electrolysis

Efficient generation of hydrogen from electrocatalytic water-splitting is of great importance to realize the hydrogen economy. In that field, designing efficient and bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) is critical for water splitting. With the increasing demands for bifunctional catalysts, a universal strategy in favor of these catalytic processes is particularly important. Herein, a variety of Zr-doped layered double hydroxide (LDH) with low-crystalline grown on nickel foam (NF) is designed to promote the bifunctional activities of electrocatalysts. It is found that the doping of Zr⁴⁺ into CoFe-LDH/NF can tune the electronic structure and also expose abundant catalytic active sites to enhance the electrocatalytic activities. In 1 M KOH, the as-prepared CoFeZr/NF exhibits superior OER and HER activities with low overpotentials of 233 and 159 mV at 10 mA cm^-2. When tested in alkaline simulated seawater electrolyte, CoFeZr/NF also shows high catalytic activities with almost no attenuation when compared with that in 1.0 M KOH. This work will provide a new way for the development of seawater electrolysis for large-scale hydrogen production.