High pCO₂ Reduces Sensitivity to CO₂ Perturbations on Temperate, Earth-like Planets Throughout Most of Habitable Zone

The nearly logarithmic radiative impact of CO₂ means that planets near the outer edge of the liquid water habitable zone (HZ) require ∼10⁶ × more CO₂ to maintain temperatures that are conducive to standing liquid water on the planetary surface than their counterparts near the inner edge. This logarithmic radiative response also means that atmospheric CO₂ changes of a given mass will have smaller temperature effects on higher pCO₂ planets. Ocean pH is linked to atmospheric pCO₂ through seawater carbonate speciation and calcium carbonate dissolution/precipitation, and the response of pH to changes in pCO₂ also decreases at higher initial pCO₂. Here, we use idealized climate and ocean chemistry models to demonstrate that CO₂ perturbations large enough to cause catastrophic changes to surface temperature and ocean pH on temperate, low-pCO₂ planets in the innermost region of the HZ are likely to have much smaller effects on planets with higher pCO₂, as may be the case for terrestrial planets with active carbonate-silicate cycles receiving less instellation than the Earth. Major bouts of extraterrestrial fossil fuel combustion or volcanic CO₂ outgassing on high-pCO₂ planets in the mid-to-outer HZ should have mild or negligible impacts on surface temperature and ocean pH. Owing to low pCO₂, Phanerozoic Earth's surface environment may be unusually volatile compared with similar planets receiving lower instellation.