One-pot Synthesis of a Truncated Cone-shaped Porphyrin Macrocycle and Its Self-assembly into Permanent Porous...

Here, we report the synthesis of a truncated cone-shaped triangular porphyrinic macrocycle, P₃ L₃ , via a single step imine condensation of a cis-diaminophenylporphyrin and a bent dialdehyde-based linker as building units. X-ray diffraction analysis reveals that the truncated cone-shaped P₃ L₃ molecules are stacked on top of each other by π⋯π and CH⋯π interactions, to form 1.7 nm wide hollow columns in the solid state. The formation of the triangular macrocycle is corroborated by quantum chemical calculations. The permanent porosity of the P₃ L₃ crystals is demonstrated by several gas sorption experiments and powder X-ray diffraction analysis.