Synthesis and Characterization of Tungsten Suboxide W_nO_3n-1 Nanotiles

W_nO_3n-1 nanotiles, with multiple stoichiometries within one nanotile, were synthesized via the chemical vapour transport method. They grow along the [010] crystallographic axis, with the thickness ranging from a few tens to a few hundreds of nm, with the lateral size up to several µm. Distinct surface corrugations, up to a few 10 nm deep appear during growth. The {102}_r crystallographic shear planes indicate the W_nO_3n-1 stoichiometries. Within a single nanotile, six stoichiometries were detected, namely W₁₆O₄₇ (WO_2.938), W₁₅O₄₄ (WO_2.933), W₁₄O₄₁ (WO_2.928), W₁₃O₃₈ (WO_2.923), W₁₂O₃₅ (WO_2.917), and W₁₁O₃₂ (WO_2.909), with the last three never being reported before. The existence of oxygen vacancies within the crystallographic shear planes resulted in the observed non-zero density of states at the Fermi energy.