In-situ constructing nanostructured magnesium ferrite on steel slag for Cr(VI) photoreduction

An innovative method is created for transforming iron-rich RO phase (MgO_0.239FeO_0.761) on steel slag surface into nanostructured Mg_0.04Fe_2.96O₄ layer. The phase change process is investigated, and it is found that salicylic acid modification and alkaline roasting procedures remarkably increase the specific surface area from 0.46 m²/g (raw steel slag) to 69.5 m²/g (Mg_0.04Fe_2.96O₄), and the generation of Mg_0.04Fe_2.96O₄ enhances the absorption of visible light and Cr(VI) conversion with 2-times increasement than raw steel slag. Surface complexation between H₂C₂O₄ ligands and Fe metal moiety on Mg_0.04Fe_2.96O₄ induces the intramolecular electron transfer under visible light irradiation based on a ligand-to-metal charge transfer mechanism, thus resulting in Cr(VI) photoreduction, and the catalytic efficiency is above 90% for Cr(VI) (40 mg/L) under inherent pH= 5.5 conditions. Moreover, recyclability tests based on magnetic separation show that the photoreactivity is closely related to Mg content of Mg_0.04Fe_2.96O₄ layer where Mg leaching occurs and finally generates cubic spinel configuration Fe₃O₄. This work highlights the importance of surface functionalization in post-use phases of steel slag in which surface reactivity and application potential can be greatly altered by chemical exposure history and surface transformations. It also provides valuable references for studying the metastable state mechanism of magnesium ferrite photocatalysts.