Highly siderophile element depletion in the Moon
James M D Day1, Richard J Walker2
1Geosciences Research Division, Scripps Institution of Oceanography, La Jolla, CA 92093-0244, USA.
Summary
This study analyzed highly siderophile element (HSE) and Os isotope data in lunar mare basalts. Results indicate a homogeneous lunar interior with low HSE abundances, consistent with late accretion before crust formation.
Area of Science:
- Geochemistry
- Isotope Geochemistry
- Planetary Science
Background:
- Lunar mare basalts provide insights into the Moon's mantle composition and evolution.
- Highly siderophile elements (HSEs) are crucial tracers of planetary formation and differentiation processes.
- Osmium (Os) isotopes offer a sensitive tool for tracking mantle evolution and accretion history.
Purpose of the Study:
- To determine the abundance and isotopic composition of HSEs in various lunar mare basalts.
- To constrain the origin and evolution of the lunar mantle.
- To investigate the nature and timing of late accretion on the Moon.
Main Methods:
- Analysis of coupled 187Os/188Os and HSE abundance data.
- Samples include Apollo mare basalts (12, 15, 17) and lunar meteorites (LAP 04841, MIL 05035).
- Modeling of partial melting and fractional crystallization processes.
Main Results:
- Most magnesian samples show chondrite-relative HSE abundances and chondritic initial 187Os/188Os.
- Mare basalts exhibit consistently low HSE abundances (~2x10^-5 to 2x10^-7 chondritic abundance).
- Apollo 12 basalts yield a Re-Os age of 3.0 ±0.6 Ga with an initial 187Os/188Os of 0.109 ±0.008.
Conclusions:
- Lunar mare basalt compositions suggest partial melting of metal-free sources with low HSE concentrations.
- Homogeneous HSE abundances across different lunar sites indicate a well-mixed lunar interior.
- Low HSE abundances and chondritic Re/Os ratios support ~0.02% late accretion prior to lunar crust formation.
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