Well-designed oxidized Sb/g-C₃N₄ 2D/2D nanosheets heterojunction with enhanced visible-light photocatalytic...

2D/2D heterojunction photocatalysts with excellent photocatalytic activity highlight considerable potential in water disinfection. Here, an oxidized Sb/g-C₃N₄ 2D/2D nanosheets heterojunction (Sb-SbO_x/CNS) was constructed based on a facile one-step liquid-phase exfoliation method using concentrated sulfuric acid. By doing so, bulk Sb and g-C₃N₄ were exfoliated simultaneously and then, intercalated each other. Compared with CNS and Sb-SbO_x, the obtained Sb-SbO_x/CNS demonstrated better photocatalytic disinfection activity towards Escherichia coli K-12 (E. coli K-12) under visible light irradiation. The 5% oxidized Sb/g-C₃N₄ 2D/2D nanosheets heterojunction (5.0% Sb-SbO_x/CNS) exhibited the best photocatalytic performance and admirable cycling stability, which was ascribed to the unique structure where the interfacial charge separation was strengthened by the strong coupling effect between Sb-SbO_x and CNS. Meanwhile, the fundamental mechanism of photocatalytic disinfection was also proposed. The photogenerated ROS (reactive oxygen species) violently attacked the E. coli K-12 membrane, creating massive and irreparable holes on the cell membrane. The leakage of cations (K⁺, Na⁺, Ca²⁺ and Mg²⁺), adenosine triphosphate, total soluble sugar and protein accelerated the destruction of E. coli K-12. Trapping experiments suggested that the photocatalytic disinfection process against E. coli K-12 was dominated by h⁺ generated on 5.0% Sb-SbO_x/CNS. This work offers a new promising way to modify the 2D/2D heterojunction featuring efficient photocatalytic disinfection performance.