Visible Light-Driven Reforming of Lignocellulose into H₂ by Intrinsic Monolayer Carbon Nitride

The photoreforming of lignocellulose is a novel method to produce clean and sustainable H₂ energy. However, the catalytic systems usually show low activity under ultraviolet light; thus, this reaction is very limited at present. Visible light-responsive metal-free two-dimensional graphite-phased carbon nitride (g-C₃N₄) is a good candidate for photocatalytic hydrogen production, but its activity is hindered by a bulky architecture. Although reported layered g-C₃N₄ modified with active functional groups prepared by the chemical exfoliation enhances the photocatalytic activity, it lost the intrinsic structure and thus is not conducive to understand the structure-activity relationship. Herein, we report an intrinsic monolayer g-C₃N₄ (∼0.32 nm thickness) prepared by nitrogen-protected ball milling in water, which shows good performance of photoreforming lignocellulose to H₂ driven by visible light. The exciton binding energy of g-C₃N₄ was estimated from the temperature-dependent photoluminescence spectra, which is a key factor for subsequent charge separation and energy transfer. It is found that monolayer g-C₃N₄ with smaller exciton binding energy increases the free exciton concentrations and promotes the separation efficiency of charge carriers, thereby effectively improving its performance of photocatalytic reforming of lignocellulose, even the virgin lignocellulose and waste lignocellulose. This result could lead to more active catalysts to photoreform the raw biomass, making it possible to provide clean energy directly from locally unused biomass.