Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Crystal Growth: Principles of Crystallization01:25

Crystal Growth: Principles of Crystallization

3.3K
Crystallization is a phase transformation process in which crystals are precipitated from a supersaturated solution or formed from other sources. During crystallization, atoms or molecules arrange themselves into a well-defined, rigid crystal lattice to minimize energy.
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
3.3K
Structures of Solids02:22

Structures of Solids

16.0K
Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
16.0K
Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

3.4K
Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
3.4K
Metallic Solids02:37

Metallic Solids

19.6K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
19.6K
Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

28.5K
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
28.5K
Molecular Models02:00

Molecular Models

41.8K
Physical models representing molecular architectures of chemical compounds play essential roles in understanding chemistry. The use of molecular models makes it easier to visualize the structures and shapes of atoms and molecules.
41.8K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Single-Crystalline Twelve-Connected Nanographene-Based Covalent Organic Frameworks.

Journal of the American Chemical Society·2026
Same author

Unraveling Water Sorption in Single-Crystal MOFs: Insights from Spectroscopy and Modeling on the Role of Structure, Composition, and Guest Molecules.

Small (Weinheim an der Bergstrasse, Germany)·2026
Same author

Porphyrin-based zinc metal-organic framework loaded with gallic acid as a novel nanoplatform exhibiting H<sub>2</sub>O<sub>2</sub>-activated reactive oxygen species generation and cytotoxicity in breast cancer cells.

RSC advances·2026
Same author

Synthesis of Highly Crystalline Covalent Organic Frameworks Using Large Language Models.

Journal of the American Chemical Society·2026
Same author

Material Preparation Information File (MPIF): A Community-Driven Standard for Reporting MOF Syntheses.

Advanced materials (Deerfield Beach, Fla.)·2026
Same author

Uniform Covalent Polymerization of Zirconium-Organic Cages for High-Loading CO<sub>2</sub> Separation Membranes.

Journal of the American Chemical Society·2026

Related Experiment Video

Updated: Oct 21, 2025

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
08:42

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

13.6K

From Molecules to Frameworks to Superframework Crystals.

Zhe Ji1, Ralph Freund2, Christian S Diercks1

  • 1Department of Chemistry, University of California-Berkeley, Berkeley, CA, 94720, USA.

Advanced Materials (Deerfield Beach, Fla.)
|September 9, 2021
PubMed
Summary

Researchers propose augmented reticular chemistry to build complex chemical structures. This strategy links molecular building blocks into progressively complex frameworks and supercrystals for advanced functionality.

Keywords:
augmented reticular chemistrymetal-organic frameworkssupercrystalssuperframeworks

More Related Videos

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
05:26

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Published on: February 10, 2023

3.1K
Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

48.5K

Related Experiment Videos

Last Updated: Oct 21, 2025

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
08:42

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

13.6K
Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks
05:26

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Published on: February 10, 2023

3.1K
Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

48.5K

Area of Science:

  • Materials Science
  • Supramolecular Chemistry
  • Chemical Synthesis

Background:

  • Achieving biological system complexity in synthetic chemical structures remains a significant challenge.
  • Existing reticular chemistry methods link metal complexes and organic molecules into frameworks.

Purpose of the Study:

  • To present a general synthetic strategy for building complex chemical structures.
  • To extend reticular chemistry principles to create higher-order assemblies like supercrystals.

Main Methods:

  • Utilizing a building block approach for progressive complexity.
  • Applying augmented reticular chemistry to link molecular constructs.
  • Extending framework assembly to crystal assembly into superframworks.

Main Results:

  • Demonstrated a strategy for creating progressively complex molecular architectures.
  • Successfully linked reticular frameworks into supercrystals (superframeworks).
  • Developed systems with enhanced dynamics and functionality beyond current materials.

Conclusions:

  • The proposed augmented reticular chemistry strategy enables the construction of highly complex and functional chemical systems.
  • This approach allows molecular-level control to be translated into macroscopic properties.
  • The developed superframworks offer potential for advanced applications requiring dynamic and complex functionalities.