An Overlooked Natural Hydrogen Evolution Pathway: Ni²⁺ Boosting H₂ O Reduction by Fe(OH)₂ Oxidation during...

Natural hydrogen (H₂ ) has gained considerable attentions as a renewable energy resource to mitigate the globally increasing environmental concerns. Low-temperature serpentinization (<200 °C) as a typical water-rock reaction is a major source of the natural H₂ . However, the reaction mechanism and the controlling step to product H₂ remained unclear, which hinders the further utilization of natural H₂ . Herein, we demonstrated that the H₂ production rate could be determined by the Fe(OH)₂ oxidation during low-temperature serpentinization. Moreover, the co-existence of Ni²⁺ could largely enhance the H₂ production kinetics. With the addition of only 1 % Ni²⁺ , the H₂ production rate was remarkably enhanced by about two orders of magnitude at 90 °C. D₂ O isotopic experiment and theoretical calculations revealed that the enhanced H₂ production kinetics could be attributed to the catalytic role of Ni²⁺ to promote the reduction of H₂ O.