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Multiphase Microreactors Based on Liquid-Liquid and Gas-Liquid Dispersions Stabilized by Colloidal Catalytic
Dmytro Dedovets1,2, Qingyuan Li1, Loïc Leclercq3
1Eco-Efficient Products and Processes Laboratory (E2P2L), UMI 3464 CNRS-Solvay, 3966 Jin Du Road, Xin Zhuang Ind Zone, 201108, Shanghai, China.
Angewandte Chemie (International Ed. in English)
|September 16, 2021
Summary
Pickering emulsions, stabilized by particles, offer sustainable microreactors for eco-efficient reactions using biobased reagents. This review covers their progress, challenges, and advanced applications in multiphase systems.
Area of Science:
- Colloid and Surface Science
- Chemical Engineering
- Green Chemistry
Background:
- Pickering emulsions, foams, bubbles, and marbles are colloidal dispersions stabilized by solid particles.
- These systems offer unique platforms for developing sustainable multiphase microreactors.
- Traditional multiphase reactors face challenges in efficiency and environmental impact.
Purpose of the Study:
- To provide a systematic overview of recent advancements in particle-stabilized dispersions as microreactors.
- To highlight their application in engineering eco-efficient reactions, particularly with biobased reagents.
- To discuss strategies for stabilizing/destabilizing these systems for product recovery and catalyst recycling.
Main Methods:
- Review of recent scientific literature on Pickering dispersions in microreactor applications.
- Analysis of physicochemical parameters governing dispersion stability.
- Exploration of advanced concepts like cascade reactions and computational methods.
Main Results:
- Particle-stabilized dispersions enable novel liquid-liquid-solid and gas-liquid-solid microreactor designs.
- These systems demonstrate potential for enhanced sustainability in multiphase reactions.
- Progress has been made in controlling dispersion stability for practical applications.
Conclusions:
- Pickering dispersions represent a promising avenue for developing sustainable and eco-efficient microreactors.
- Further research into controlling stability and integrating advanced reaction schemes is crucial.
- These systems are key to reengineering multiphase reactors for a greener future.

