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Unprecedented neptunyl(V) cation-directed structural variations in Np2O compounds.

Zhong-Fei Xu1,2, Wen-Jing Zhang1,2, Ping Zhang2

  • 1Department of Physics, University of Science and Technology Beijing, Beijing 100083, China. hushuxian@csrc.ac.cn.

Nanoscale
|September 16, 2021
PubMed
Summary

This study explores neptunium (Np) oxide clusters, revealing Np(V) as a key ion for stable structures. Mixed-valent Np(III/V) oxides are predicted, with significant 5f-orbital covalent interactions enhancing understanding of Np oxide bonding.

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