Stabilizing the Optimal Carrier Concentration in Al/Sb-Codoped GeTe for High Thermoelectric Performance

GeTe is a promising thermoelectric material and has attracted growing research interest recently. In this study, the effect of Al doping and Al&Sb codoping on the thermoelectric properties of GeTe was investigated. Due to the presence of a high concentration of intrinsic Ge vacancies, pristine GeTe exhibited a very high hole concentration and unpromising thermoelectric performance. By Sb doping in GeTe, the hole concentration can be effectively reduced, thus improving the thermoelectric performance. Aluminum, as a p-type dopant in GeTe, will increase the hole concentration and lattice thermal conductivity; thus, it has long been considered as an unfavorable dopant for the optimization of GeTe-based materials. However, when Al and Sb were codoped into GeTe, the hole concentration was effectively suppressed, and the lattice thermal conductivity can be reduced. Eventually, a maximum zT of ∼2.0 at 773 K was achieved in Al&Sb-codoped Al_0.01Sb_0.1Ge_0.89Te.