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Published on: March 18, 2015
Synthesis and Reactivity of Cationic Gallium(I) [12]Crown-4 Complexes
Jeremy L Bourque1, Robert A Nanni1, Mark C Biesinger1,2
1Department of Chemistry, University of Western Ontario, London, Ontario, Canada N6A 5B7.
Abstract:
The synthesis and reactivity of a gallium(I) cationic complex using [12]crown-4 as a stabilizing ligand were explored. The synthesis of [Ga([12]crown-4)][GaCl4] was achieved in one step from commercially available starting materials. Anion exchange was utilized to replace the reactive tetrachlorogallate anion for the perfluorophenylborate anion. [Ga([12]crown-4)][B(C6F5)4] was analyzed using XPS, which allowed for the classification of the gallium(I)-crown ether complex as electron-deficient. Reactions of the gallium(I)-crown ether complex with Cp*K and cryptand[2.2.2] demonstrated the facile synthesis of a known gallium(I) compound as well as the generation of new gallium(I) complexes, highlighting the use of the gallium(I)-crown ether complex as an effective starting material for new gallium(I) complexes.
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