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Updated: Oct 19, 2025

Preparation and Characterization of C60/Graphene Hybrid Nanostructures
Published on: May 15, 2018
Cycloparaphenylene Double Nanohoop: Structure, Lamellar Packing, and Encapsulation of C60 in the Solid State
Yong Yang1, Shangxiong Huangfu2,3, Sota Sato4
1Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland.
Abstract:
A new member of the cycloparaphenylene double-nanohoop family was synthesized. Its π-framework features two oval cavities that display different shapes depending on the crystallization conditions. Incorporation of the peropyrene bridge within the nanoring cycles via bay-regions alleviates steric effects and thus allows 1:1 complexation with C60 in the solid state. This nanocarbon adopts a lamellar packing motif, and our results suggest that the structural adjustment of this double nanohoop could enable its use in supramolecular and semiconductive materials.
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