Neutralization of bauxite residue with high calcium content in abating pH rebound by using ferrous sulfate

The high alkalinity of bauxite residue and its sustained release impose major limitation on its reuse and ecological disposal. It has been confirmed from sustained rehabilitation that gypsum can effectively reduce the alkalinity of bauxite residue by continuously releasing Ca²⁺ to react with carbonate and hydroxide. However, the combined bauxite residue with high calcium content exhibits stubborn alkalinity for most alkaline reduction methods employing cations to consume carbonate. In this study, we have aimed to address this knowledge gap by investigating the dose-response relationship in the alkaline reduction induced by ferrous sulfate (FS) neutralization. The pH, exchangeable sodium percentage (ESP), and CO₃^2-/HCO₃^- of bauxite residue decreased from 10.6, 44.1%, and 42.7/24.5 mg/kg to 8.1, 27.7%, and 0.7/18.0 mg/kg, respectively. Approximately 20-55 days were required for the neutralization reaction to reach equilibrium. The FS induced an increase in free iron oxide (Fe_d) and amorphous iron oxide (Fe_o), and partial dissolution of alkaline minerals including calcite, cancrinite, and kaolinite in bauxite residue. Further, addition of FS also affected the kinetic dissolution process of bauxite residue; the acid neutralization capacity of bauxite residue to pH 7 decreased from 0.21 mol H⁺/kg solid to 0.02 mol H⁺/kg solid. The results showed FS to be a potential candidate for improving the characteristics of the combined bauxite residue, and guide the FS application for the disposal of the combined bauxite residue.