Effect of Silver Modification on the Photoactivity of Titania Coatings with Different Pore Structures

Nanostructured photoactive systems are promising for applications such as air and water purification, including self-cleaning coatings. In this study, mesoporous TiO₂ sol-gel coatings with different pore structures were prepared and modified with silver by two methods: the "mixing" method by adding AgNO₃ to the precursor sol, and the "impregnation" method by immersing the samples in AgNO₃ solution (0.03 and 1 M) followed by heat treatment. Our aim was to investigate the effects that silver modification has on the functional properties (e.g., those that are important for self-cleaning coatings). Transmittance, band gap energy, refractive index, porosity and thickness values were determined from UV-Vis spectroscopy measurements. Silver content and structure of the silver modified samples were characterized by X-ray photoelectron spectroscopy, Rutherford backscattering spectrometry, High-resolution transmission electron microscopy and Energy Dispersive X-ray Spectrometry elemental mapping measurements. Wettability properties, including photoinduced wettability conversion behavior were investigated by water contact angle measurements. Photoactivity was studied under both UV and visible light with rhodamine 6G and methylene blue dye molecules, at the liquid-solid and air-solid interfaces modeling the operating conditions of self-cleaning coatings. Samples made with "impregnation" method showed better functional properties, in spite of their significantly lower silver content. The pore structure influenced the Ag content achieved by the "impregnation" method, and consequently affected their photoactivity.