Anisotropic Optical Response of WTe₂ Single Crystals Studied by Ellipsometric Analysis

In this paper we report the crystal growth conditions and optical anisotropy properties of Tungsten ditelluride (WTe₂) single crystals. The chemical vapor transport (CVT) method was used for the synthesis of large WTe₂ crystals with high crystallinity and surface quality. These were structurally and morphologically characterized by means of X-ray diffraction, optical profilometry and Raman spectroscopy. Through spectroscopic ellipsometry analysis, based on the Tauc-Lorentz model, we identified a high refractive index value (~4) and distinct tri-axial anisotropic behavior of the optical constants, which opens prospects for surface plasmon activity, revealed by the dielectric function. The anisotropic physical nature of WTe₂ shows practical potential for low-loss light modulation at the 2D nanoscale level.