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Optical Attenuators Extend Dynamic Range but Alter Angular Response of Planar Ultraviolet-C Dosimeters
Alison Su1, Alisha Geldert1, Samantha M Grist2
1University of California, Berkeley - University of California, San Francisco Graduate Program in Bioengineering, Berkeley, CA.
Photochemistry and Photobiology
|October 1, 2021
Summary
Optical attenuators can extend the range of photochromic indicators (PCIs) for measuring UV-C dose on N95 respirators. However, ensuring accurate UV-C dose measurement requires careful consideration of the attenuator's angular response.
Area of Science:
- * Engineering
- * Photochemistry
- * Public Health
Background:
- * Effective decontamination of N95 respirators using ultraviolet-C (UV-C) light necessitates accurate dose measurement across the entire respirator surface.
- * Photochromic indicators (PCIs) are useful for measuring UV-C dose on complex surfaces but often saturate at lower doses than required for porous materials like N95s.
- * Extending the dynamic range of PCIs is crucial for validating UV-C decontamination protocols for N95 respirators.
Purpose of the Study:
- * To investigate the use of optical attenuators to enhance the dynamic range of PCIs for UV-C dose measurement.
- * To evaluate the impact of different attenuator types (specular vs. diffuse) on PCI angular response and UV-C measurement accuracy on N95 respirators.
- * To determine the critical role of near-ideal angular response for accurate UV-C dose quantification.
Main Methods:
- * Analytical modeling of optical attenuators to predict dynamic range extension and angular response.
- * Empirical testing of PCIs stacked behind specular (borosilicate) and diffuse (polytetrafluoroethylene) attenuators.
- * Characterization of the angular response of PCI-attenuator stacks and evaluation of on-N95 UV-C dose measurement accuracy within a decontamination system.
Main Results:
- * Both specular and diffuse attenuators increased PCI dynamic range by over 4×.
- * All tested attenuators introduced angle-dependent transmittance, leading to location-dependent underestimation of UV-C dose.
- * PCI-borosilicate and PCI-polytetrafluoroethylene stacks underreported UV-C dose by up to 40.8% and 19.8%, respectively, in steeply sloped locations.
Conclusions:
- * Optical attenuators can extend PCI dynamic range for UV-C dose measurement on N95 respirators.
- * The angular response of the attenuator is critical; non-ideal responses lead to significant measurement inaccuracies.
- * Verifying near-ideal angular response is essential for reliable UV-C dose validation in respirator decontamination.
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