Highly efficient electrochemical reduction of carbon dioxide to formate on Sn modified Bi₂O₃ heterostructure

In this work, Sn species are deposited onto the surface of a Bi₂O₃ material by a facile disproportionated reaction and the prepared catalyst shows a superior electrocatalytic performance towards CO₂ reduction. The deposition of Sn atoms can donate electrons to the Bi₂O₃ material and increase its electrical conductivity. The Sn_M-Bi₂O₃ catalyst with the optimal Sn content delivers a high faradaic efficiency of 95.8% at -1.0 V for formate production. In addition, the partial current density of formate can reach 41.8 mA cm^-2. The Sn_M-Bi₂O₃ catalyst also exhibits superior stability towards long-term electrolysis. The modification of Sn species not only helps to stabilize the reaction intermediate but also inhibits the hydrogen evolution reaction (HER) pathway, achieving the synergetic enhancement of catalytic activity.