Noble metal modified ReS₂ nanocavity for surface-enhanced Raman spectroscopy (SERS) analysis

The rhenium disulphide (ReS₂) nanocavity-based surface enhanced Raman scattering (SERS) substrates ware fabricated on the gold-modified silicon pyramid (PSi) by thermal evaporation technology and hydrothermal method. In this work, the ReS₂ nanocavity was firstly combined with metal nanostructures in order to improve the SERS properties of ReS₂ materials, and the SERS response of the composite structure exhibits excellent performance in sensitivity, uniformity and repeatability. Numerical simulation reveals the synergistic effect of the ReS₂ nanocavity and the plasmon resonance generated by the metal nanostructures. And the charge transfer between the metal, ReS₂ and the analytes was also verified and plays an non-ignorable role. Besides, the plasmon-driven reaction for p-nitrothiophenol (PNTP) to p,p'-dimercaptobenzene (DMAB) conversion was successfully in-situ monitored. Most importantly, it is found for the first time that the SERS properties of ReS₂ nanocavity-based substrates are strongly temperature dependent, and the SERS effect achieves the best performance at 45 °C. In addition, the low concentration detection of malachite green (MG) and crystal violet (CV) molecules in lake water shows its development potential in practical application.