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Updated: Oct 17, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
Published on: November 21, 2017
Photoredox catalysis in nickel-catalyzed C-H functionalization
Lusina Mantry1, Rajaram Maayuri1, Vikash Kumar1
1Department of Chemistry, Indian Institute of Technology Tirupati, Tirupati - Renigunta Road, Settipalli Post, Tirupati, Andhra Pradesh 517506, India.
Abstract:
Catalytic C‒H functionalization has become a powerful strategy in organic synthesis due to the improved atom-, step- and resource economy in comparison with cross-coupling or classical organic functional group transformations. Despite the significant advances in the metal-catalyzed C‒H activations, recent developments in the field of metallaphotoredox catalysis enabled C‒H functionalizations with unique reaction pathways under mild reaction conditions. Given the relative earth-abundance and cost-effective nature, nickel catalysts for photoredox C‒H functionalization have received significant attention. In this review, we highlight the developments in the field of photoredox nickel-catalyzed C‒H functionalization reactions with a range of applications until summer 2021.
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