Removal and recovery of phosphate using a novel calcium silicate hydrate composite starch cryogel

Phosphate is a major pollutant that deteriorates water quality and causes eutrophication, a novel calcium silicate hydrate composite cryogel (Cry-CSH) was thus successfully prepared for phosphate removal and recovery in this work. Calcium silicate hydrate (C-S-H) was mixed with the gel precursor (7.5% w/w) prepared from native starch and limewater (saturated calcium hydroxide solution as the cross-linker). The mixture was frozen and thawed for 3 cycles giving an interconnected macroporous composite. This had C-S-H nanoparticles (75 mg) immobilized on a monolithic floatable cryogel network (2.5 cm diameter × 1.0 cm height) enabling an easier recovery and without the losses that occur when using C-S-H nanoparticles. The phosphate adsorption reaches equilibrium at 120 min with adsorption capacity of 2.50 mgPO₄^3-/g_Cry-CSH (65.42 mgPO₄^3-/g_C-S-H) under optimum conditions. Adsorption equilibrium data were well fit by the Freundlich isotherm model, while kinetic results were well fit by the pseudo second-order model. The calculated activation energy (E_a) of 43.9 kJ/mol indicates chemical adsorption, while a positive change in enthalpy (ΔH⁰, 19.3 kJ/mol) indicates the endothermic nature of phosphate adsorption. Cry-CSH can remove phosphate from wastewater and effluent samples with excellent removal efficiency (>98%). It can float on water surface for at least 105 days without damage, while its phosphate adsorbed form can be biodegraded within 10 days under soil buried conditions. Thus, this work demonstrated the significant potential of Cry-CSH for practical and environmentally friendly phosphate removal and recovery.