Reversible transformation between Au₁₄Ag₈ and Au₁₄Ag₄ nanoclusters

Although several approaches have been exploited to trigger the structural transformation of metal nanoclusters, most cases are assigned to the unidirectional conversion, while the reversible conversion of nanoclusters remains challenging. In this work, the reversible conversion between two Au-Ag alloy nanoclusters, Au₁₄Ag₈(Dppm)₆(CN)₄Cl₄ and Au₁₄Ag₄(Dppm)₆Cl₄, has been accomplished, which was tracked by UV-vis and ESI-MS spectroscopy. The condition of the nanocluster reversible conversion has been meticulously mapped out. Our results provide some new insights into the cluster transformation, which will benefit the future preparation of metalloid clusters with customized structures and properties.