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Updated: Oct 16, 2025

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Crystal structure of [Th3(Cp*)3(O)(OH)3]2Cl2(N3)6: a discrete mol-ecular capsule built from multinuclear
Steven P Kelley1, Pokpong Rungthanaphatsophon1, Justin R Walensky1
1Department of Chemistry, University of Missouri-Columbia, Columbia, MO 65211, USA.
Abstract:
An unusually large and structurally complex charge-neutral polynuclear cluster, hexa-μ2-azido-di-μ3-chlorido-hexa-μ2-hydroxido-di-μ3-oxido-hexa-kis-(penta-methyl-cyclo-penta-dien-yl)hexa-thorium-diethyl ether-tetra-hydro-furan (1/0.56/1.44), [Th3(C10H15)6Cl3(N3)6(OH)6O2]·0.56C4H10O·1.44C4H8O or [Th3(Cp*)3(O)(OH)3]2Cl2(N3)6·0.56C4H10O·1.44C4H8O (Cp* = [penta-methyl-cyclo-penta-dien-yl])-, has been crystallized as a mixed tetra-hydro-furan/diethyl ether solvate and structurally characterized. The mol-ecule contains a number of unusual features, the most notable being a finite yet exceptionally long cyclic metal-azido chain. These rare features are the consequence of both sterically protecting Cp* ligands and highly bridging oxide and hydroxide ligands in the same system and illustrate the inter-esting new possibilities that can arise from combining organometallic and solvothermal f-block element chemistry.
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