Reduced Graphene-Oxide-Encapsulated MoS₂/Carbon Nanofiber Composite Electrode for High-Performance Na-Ion Batteries

Sodium-ion batteries (SIBs) have been increasingly studied due to sodium (Na) being an inexpensive ionic resource (Na) and their battery chemistry being similar to that of current lithium-ion batteries (LIBs). However, SIBs have faced substantial challenges in developing high-performance anode materials that can reversibly store Na⁺ in the host structure. To address these challenges, molybdenum sulfide (MoS₂)-based active materials have been considered as promising anodes, owing to the two-dimensional layered structure of MoS₂ for stably (de)inserting Na⁺. Nevertheless, intrinsic issues of MoS₂-such as low electronic conductivity and the loss of active S elements after a conversion reaction-have limited the viability of MoS₂ in practical SIBs. Here, we report MoS₂ embedded in carbon nanofibers encapsulated with a reduced graphene oxide (MoS₂@CNFs@rGO) composite for SIB anodes. The MoS₂@CNFs@rGO delivered a high capacity of 345.8 mAh g^-1 at a current density of 100 mA g^-1 for 90 cycles. The CNFs and rGO were synergistically taken into account for providing rapid pathways for electrons and preventing the dissolution of S sources during repetitive conversion reactions. This work offers a new point of view to realize MoS₂-based anode materials in practical SIBs.