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Updated: Oct 15, 2025

Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
Multi-responsive deep-ultraviolet emission in praseodymium-doped phosphors for microbial sterilization
Xinquan Zhou1, Jianwei Qiao1, Yifei Zhao1
1The State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Technology, South China University of Technology, Guangzhou, 510641 China.
Researchers developed a novel deep-ultraviolet (UV) emitting material using a heterovalent substituting strategy. This multi-responsive material can be activated by various light sources for potential sterilization applications.
Area of Science:
- Materials Science
- Solid State Chemistry
- Luminescence
Background:
- Developing multimode luminescent materials activated by diverse sources is challenging.
- Existing materials often lack multi-responsive emission within a single system.
Purpose of the Study:
- To realize multimode deep-ultraviolet (UV) emission in a single system.
- To explore heterovalent substituting strategy for novel luminescent material design.
Main Methods:
- Utilized a heterovalent substituting strategy with Pr3+ in Li2CaGeO4 (LCGO) host.
- Investigated defect site reconstruction, including cation defects and oxygen vacancies.
- Analyzed persistent luminescence, photo-stimulated luminescence, and up-conversion luminescence.
Main Results:
- Achieved multimode deep-UV emission from defect-rich LCGO:Pr3+.
- Demonstrated synergetic persistent and photo-stimulated luminescence.
- Observed up-conversion luminescence converting visible light to deep-UV radiation.
- LCGO:Pr3+ responded to X-rays, UV lamps, and lasers.
Conclusions:
- The developed LCGO:Pr3+ exhibits multi-responsive deep-UV emission.
- A dual-mode optical conversion strategy for bacterial inactivation was fabricated.
- This work provides insights into UV light sources for sterilization and multi-mode luminescent material construction.
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