Co-Salen Complex-Derived CoP Nanoparticles Confined in N-Doped Carbon Microspheres for Stable Sodium Storage

The poor rate and cycle performance rooting from the inferior electrical conductivity and large volume change are bottlenecks for further application of the potential anode material in sodium-ion batteries. To address this problem, homogeneous CoP nanoparticles enwrapped in the N-doped carbon (CoP/NC) microspheres are synthesized by the simultaneous carbonization and phosphorization of Co-salen complex microspheres for the first time. The N-doped carbon enhances its conductivity and diminishes the volume stress, and the dispersed CoP nanoparticles in carbon provide more reaction sites, resulting in a superior sodium storage performance. CoP/NC microspheres exhibit the capacity of 373 mA h g^-1 at 0.1 A g^-1 after 100 cycles. Even at 2 A g^-1 for 2000 cycles, the capacity of 195 mA h g^-1 is also achieved. This work provides an excellent reference for the design and synthesis of sulfide, selenide, and other transition-metal composites. It is also beneficial to expand the application of salen complexes in the design and synthesis of catalysts and energy storage materials.