The gelling behavior of gellan in the presence of different sodium salts

It is well known that metal ions have great effects on gelling behaviors of gellan aqueous systems, however, the effects of their co-ions - anions have rarely been studied. Herein, we investigated the effects of four kinds of sodium salts with different anions (NaCl, CH₃COONa, Na₂C₂O₄ and Na₃C₆H₅O₇) on gelling behaviors of gellan aqueous systems in terms of gelling temperature and gel hardness. It was found that, when [Na⁺] was low (20 mM), the salt with Cl^- or CH₃COO^- favored the gelling of gellan aqueous systems, while the salt with C₂O₄^2- or C₆H₅O₇^3- took adverse effects probably because C₂O₄^2- or C₆H₅O₇^3- could react with divalent cations (Ca²⁺ and Mg²⁺) in gellan to form precipitates or chelates and break their interactions with gellan (salt bridges). When [Na⁺] was high (50 or 80 mM), all the four kinds of salts facilitated gelling due to the shielding effects of high concentrations of Na⁺ on the negative charges along the gellan chains, and followed the order of: Cl^- > CH₃COO^- > C₂O₄^2- > C₆H₅O₇^3-. This study demonstrates the effects of anion kind of salts on gelling behaviors of gellan aqueous systems and provides references for the application of gellan.