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Updated: Oct 14, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
Excited-state Dynamics of Radical Ions in Liquids
Jakob Grilj1, Joseph S Beckwith2, Eric Vauthey3
1Dept. of Physical Chemistry, University of Geneva, 30 quai Ernest-Ansermet, CH-1220 Geneva; Present address: AWK Group AG, Leutschenbachstrasse 45, CH-8050 Zurich, Switzerland.
Abstract:
Thomas Bally has acquired international recognition for his work on the photochemistry of reactive intermediates, which include radical ions. Here, we present a brief overview of our investigations of the excited-state dynamics of radical ions in liquids at room temperature, which are still poorly documented. A better understanding of these dynamics is most relevant, as open-shell ions in the excited state are being increasingly used in redox photochemistry and have been proposed to play a key role in highly exergonic photoinduced electron transfer reactions.
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