Combination of biodegradation and fenton process for efficient removal of PDM/ZnO

In the present study, an investigation was conducted on the removal of polydiallyldimethylammonium chloride-acrylic-acrylamide-hydroxyethyl acrylate/ZnO nanocomposites (PDM/ZnO) through biodegradation and Fenton process coupled treatments. As revealed from the results of the chemical oxygen demand, the total organic carbon, the biochemical oxygen demand and the CO₂ production analysis, PDM/ZnO could be partially biodegraded. The optimal initial pH, the mixed liquid suspended solids concentration and additional carbon source (glucose) dosage in the biodegradation were 7.0, 4.0 g/L and 1.0 g/L, respectively. On the whole, NaCl, the coexisted metal cations (Cu²⁺, Zn²⁺ and Cr³⁺) and additional NH₄Cl inhibited the biodegradation of PDM/ZnO. PDM/ZnO was suggested to adversely affect on microbial community structure and activity. Optimum conditions for Fenton treatment were 50 mg/L Fe²⁺, 20 mL/L H₂O₂ and pH 2.0. Biodegradation showed that 64% of PDM/ZnO was removed. Besides, the combination of Fenton post-treatment could achieve an over 97% removal of PDM/ZnO. Thus, Fenton process combined biodegradation pre-treatment can act as an effective method to remove PDM/ZnO.