Surface ligand engineering of CsPbBr₃ perovskite nanowires for high-performance photodetectors

Surface ligand engineering is of great importance for the preparation of one-dimensional (1D) CsPbBr₃ nanowires for high-performance photodetectors. The traditional long-chain terminated ligands such as oleylamine/oleic acid (C18) used in the preparation of CsPbBr₃ nanowires will form an electrically insulating layer on the surface of the nanowires, which hinders the effective transport of charge carriers in optoelectronic devices. In this paper, short-chain ligands, including dodecylamine/dodecanoic acid (C12), octylamine/octanoic acid (C8) and hexylamine/hexanoic acid (C6), are introduced to partially replace long-chain ligands (C18) to successfully prepare various CsPbBr₃ nanowires via a solvothermal method. Microstructure characterization indicates that the four kinds of nanowires before/after surface ligand engineering, which are named as C18-CsPbBr₃, C12/18-CsPbBr₃, C8/18-CsPbBr₃ and C6/18-CsPbBr₃, all have high aspect ratio and purity. As compared with CsPbBr₃ with long-chain terminated ligands, the C8/18-CsPbBr₃ and C6/18-CsPbBr₃ nanowires with shorter chain ligands exhibit superior photoluminescence (PL) performance and stability under adverse conditions such as ultraviolet irradiation and high temperature. The constructed photodetectors based on C8/18-CsPbBr₃ and C6/18-CsPbBr₃ nanowires have shown improved performances. This work provides a new idea for the preparation of CsPbBr₃ nanowires with high optical properties, stability and charge transport, and the prepared CsPbBr₃ nanowires have potential application prospects in optoelectronic devices.