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Updated: Oct 13, 2025
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Combined Experimental/Theoretical Study on the Luminescent Properties of Homoleptic/Heteroleptic Erbium(III)
Suchithra Ashoka Sahadevan1,2, Fabio Manna1, Alexandre Abhervé2
1Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, S.S. 554, Bivio per Sestu, Monserrato, Cagliari I-09042, Italy.
Abstract:
The synthesis, structural and photophysical characterization, and theoretical studies on homo/heteroleptic neutral 2D-layered coordination polymers (CPs), obtained by combining the ErIII ion with chlorocyananilate (ClCNAn) and/or tetrafluoroterephthalate (F4BDC) linkers, are herein reported. The structure of the heteroleptic ErIII-based CP, formulated as [Er2(ClCNAn)2(F4BDC)(DMSO)6] (1) is also reported. 1 crystallizes in the triclinic P1̅ space group, and the structure consists of neutral 2D layers formed by ErIII ions linked through the two linkers oriented in such a way that the neighboring 2D layers are eclipsed along the a axis, leading to parallelogram-like cavities. Photophysical measurements highlight the prominent role of chlorocyananilate linkers as optical antennas toward lanthanide ions, while wave-function-theory analysis supports the experimental findings, providing evidence for the effect of ligand substitution on the luminescence properties of homo/heteroleptic 2D CPs.
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