Composition-dependent activity of Zn_xCd_1-xSe solid solution coupled with Ni₂P nanosheets for visible-light-driven...

Metal selenide semiconductors have been rarely used for photocatalytic water splitting because of their poor stability and severe photocorrosion properties. Hence, designing stable metal selenides with suitable bandgap energies has considerable practical significance in photocatalytic H₂ evolution. In this work, a novel series of Zn_xCd_1-xSe (x = 0 ∼ 1) with tunable band structure were fabricated through a simple solvothermal method. Impressively, the ZnSe exhibited a maximum H₂ production rate of 1056 µmol g^-1h^-1, which was higher than that of CdSe and Zn_xCd_1-xSe solid solutions. Such visible-light photoactivity for water reduction to H₂ was attained even after 6 cycling photocatalytic experiments. Moreover, the two-dimensional (2D) Ni₂P nanosheets act as a high-efficiency cocatalyst integrated with Zn_xCd_1-xSe semiconductor to boost photocatalytic H₂ generation performance. The optimal 8% Ni₂P/ZnSe composites displayed excellent cycling stability and superior photocatalytic H₂ evolution performance (4336 µmol g^-1h^-1), which was about 4.1 times that of pure ZnSe under visible light irradiation. Photoelectrochemical (PEC), photoluminescence (PL), and time-resolved photoluminescence (TRPL) measurements reveal that the improved photoactivity Ni₂P/ZnSe photocatalysts were ascribed to the effective separation and migration of photoinduced carriers. The present work paves a pathway to explore the fabrication of Zn_xCd_1-xSe solid solutions and the hybridization of 2D transition metal phosphides nanosheets toward photocatalytic applications.